Learn what "she knows i'm not a big shot ceo" means, when people say it, and how to use it naturally in English.

It means the speaker is rejecting the idea that the man is a big-shot executive or very important person.
From Married To A Stranger, Episode 46
The speaker is clarifying that she knows he is not powerful or important.
Use this to deny someone's status or power in a conversation. It is more specific to context and not very reusable as a standalone phrase.
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